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Low-Volume Fraction Colloidal Assembly


Principal Investigator: Arjun G. Yodh, Univ. of Pennsylvania
Project Scientist: Allen Wilkinson, Glenn Research Center
Project Manager: Susan Motil, Glenn Research Center

Currently scheduled to be launched: Flight #UF-6 - Date 01/2007

Why:
Simple colloidal self-assembly may produce photonic crystals for optical telecommunications.
The thermodynamics of self-assembly is not understood for a diversity of useful materials (e.g. semi-conductor colloids in water, and micro-structures in the cell cytoplasm).
Low-g is the only place one can grow very open porous ordered structures or use very dense semiconductor particles with photonic behavior.

How:
Use low volume fraction suspensions of a large particle-small particle mixture like ZnS large particles in soap and water, where soap micelles are the small particles.  These assemblies will be examined microscopically in-situ and  for the angular and wavelength dependence of reflected light. ZnS and water have a large index of refraction mismatch needed for satisfactory photonic response.  Their 4:1 density ratio makes self assembly impossible in 1-g. Surface templates are used to induce colloidal crystals of open structures (e.g. BCC) that will collapse in 1-g due to the weak entropic binding.
 
 

Liquid Bridge in Microgravity
 Photonic crystals transmit only certain wavelength ranges and in certain directions.  Surface templates control growth of diverse open crystal structures.

Impact/Benefits:
Photonic materials can act as light guides and light valves for fiber optic communications in very small volumes.
The understanding of the thermodynamics of entropically driven self-assembly may have bearing on biological intra-cellular structural changes.

Low-Volume Fraction Colloidal Assembly

*Next Flight Experiment: Micromechanics of Magnetorheological Fluids

This experiment is to be flown in the Light Microscopy Module (LMM) aboard the International Space Station.

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